We report a novel method for the synthesis of stable, OH free zinc oxide qu
antum dots, using an electrochemical route. The optical properties of these
quantum dots were studied at room temperature, by taking the optical absor
ption and luminescence spectra. The band gap luminescence is predominant in
ZnO quantum dots synthesized by the present technique, while the green def
ect induced luminescence, typical of ZnO, is strongly quenched. The role of
defects in photoluminescence emission is discussed. (C) 1999 American Inst
itute of Physics. [S0021-8979(99)05505-X].