P. Van Landuyt et al., Comparison of surface treatment methods for promoting the adhesion of glass on titanium, J MATER SCI, 33(20), 1998, pp. 4991-4999
A glass allowing the wetting of titanium has previously been developed. Two
surface treatments promoting glass adhesion on titanium are compared: preo
xidation and phosphatation combined with preoxidation. After preoxidation a
t 700 degrees C, a 1 mu m-thick TiO2 layer covers titanium. The phosphated
titanium substrates are oxidized at 600 degrees C to obtain a 20 mu m-thick
oxifluoride layer. After firing, glass adhesion is obtained with both surf
ace treatments, but a "critical time of firing" appears with preoxidized ti
tanium. WDS analysis suggests that diffusion of TiO2 into the glass is resp
onsible for adhesion on preoxidized titanium, while a complex oxifluoride l
ayer allows redox phenomena in the case of phosphated titanium. Pull-off te
sts have measured a maximum strength from 1.5 to 3 MPa whatever the surface
treatment. Measurement of transverse crack densities in the vitreous coati
ngs gives a higher value for phosphated than for preoxidized titanium. This
confirms that better adhesion is obtained after phosphatation treatment. (
C) 1998 Kluwer Academic Publishers.