The titania coatings have been deposited on polyethylene terephtalate
(PET) by r.f. magnetron sputtering in an oxygen-argon plasma from a pu
re titanium target. The titania films always consist of a mixture of a
morphous and crystallized phases of the anatase structure. The composi
tion (O/Ti atomic ratio) established by Rutherford backscattering spec
trometry depends on the deposition parameters and mainly on the oxygen
partial pressure. The crystallinity, the compactness, the stresses an
d the gas barrier effect of the titania coatings increase with the kin
etic energy of the sputtered particles. This varies in the same way as
the r.f. power and in the opposite manner to the oxygen partial press
ure. The refractive index increases all along with the compactness of
the titania film; the extinction coefficient decreases and the optical
bandgap values increase when the O/Ti atomic ratio increases. Good ad
hesion of a titania coating on a PET film needs at the same time activ
ation of the surface of the PET by a CO, plasma treatment and optimiza
tion of the sputtering parameters.