Kinetics and mechanism of the dehydrohalogenation of Ar2CHCX3 and Ar2CHCHX2 by strong N-bases

Authors
Schroeder, G Leska, B Gierczyk, B Rozalski, B Brzezinski, B
Citation
G. Schroeder et al., Kinetics and mechanism of the dehydrohalogenation of Ar2CHCX3 and Ar2CHCHX2 by strong N-bases, J MOL STRUC, 476(1-3), 1999, pp. 173-179
Citations number
22
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR STRUCTURE
ISSN journal
00222860 → ACNP
Volume
476
Issue
1-3
Year of publication
1999
Pages
173 - 179
Database
ISI
SICI code
0022-2860(19990223)476:1-3<173:KAMOTD>2.0.ZU;2-W
Abstract
The kinetics and mechanism of the elimination reactions of 1,1,1-trifluoro- , 1,1,1-trichloro-, 1,1,1-tribromo-, 1,1-dichloro- and 1, 1-dibromo-2,2-bis (4-nitrophenyl)ethanes and two strong N-bases: 1,5,7-triazabicyclo[4.4.0]de c-5-ene (TBD) and 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene (MTBD) are d iscussed. (C) 1999 Elsevier Science B.V. All rights reserved.