G. Diezemann et al., Slow secondary relaxation in a free-energy landscape model for relaxation in glass-forming liquids, PHYS REV E, 59(2), 1999, pp. 2067-2083
Within the framework of a free-energy landscape model for the relaxation in
supercooled liquids the primary (alpha) relaxation is modeled by transitio
ns among different free-energy minima. The Secondary (beta) relaxation then
corresponds to intraminima relaxation. We consider a simple model for the
reorientational motions of the molecules associated with both processes and
calculate the dielectric susceptibility as well as the spin-lattice relaxa
tion times. The parameters of the model can be chosen in a way that both qu
antities show a behavior similar to that observed in experimental studies o
n supercooled liquids. In particular we find that it is not possible to obt
ain a crossing of the time scales associated with alpha and beta relaxation
. In our model these processes always merge at high temperatures and the cr
process remains above the merging temperature. The relation to other model
s is discussed.