Slow secondary relaxation in a free-energy landscape model for relaxation in glass-forming liquids

Citation
G. Diezemann et al., Slow secondary relaxation in a free-energy landscape model for relaxation in glass-forming liquids, PHYS REV E, 59(2), 1999, pp. 2067-2083
Citations number
50
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW E
ISSN journal
1063651X → ACNP
Volume
59
Issue
2
Year of publication
1999
Part
B
Pages
2067 - 2083
Database
ISI
SICI code
1063-651X(199902)59:2<2067:SSRIAF>2.0.ZU;2-W
Abstract
Within the framework of a free-energy landscape model for the relaxation in supercooled liquids the primary (alpha) relaxation is modeled by transitio ns among different free-energy minima. The Secondary (beta) relaxation then corresponds to intraminima relaxation. We consider a simple model for the reorientational motions of the molecules associated with both processes and calculate the dielectric susceptibility as well as the spin-lattice relaxa tion times. The parameters of the model can be chosen in a way that both qu antities show a behavior similar to that observed in experimental studies o n supercooled liquids. In particular we find that it is not possible to obt ain a crossing of the time scales associated with alpha and beta relaxation . In our model these processes always merge at high temperatures and the cr process remains above the merging temperature. The relation to other model s is discussed.