The peculiarities of the electrochemical behavior of copper perchlorate solutions in the presence of amino acids

Citation
Mv. Rylkina et al., The peculiarities of the electrochemical behavior of copper perchlorate solutions in the presence of amino acids, PROT MET R, 35(1), 1999, pp. 23-27
Citations number
16
Categorie Soggetti
Metallurgy
Journal title
PROTECTION OF METALS
ISSN journal
00331732 → ACNP
Volume
35
Issue
1
Year of publication
1999
Pages
23 - 27
Database
ISI
SICI code
0033-1732(199901/02)35:1<23:TPOTEB>2.0.ZU;2-3
Abstract
The effect of a number of monoamino carbonic acids on the anodic dissolutio n of copper in perchlorate solutions was studied spectrophotometrically and voltammetrically. An investigation of the position and intensity of the pe aks of cathodic polarization curves depending on the concentration of amino acids was shown to provide additional information on the mechanism of the anodic ionization of copper. A scheme of the process that involves intermed iate stages with the participation of amino acid anions is proposed.