Synthesis of a novel azidocastasterone derivative as a potential photoaffinity label for the brassinosteroid receptor

Authors
Back, TG Minksztym, K
Citation
Tg. Back et K. Minksztym, Synthesis of a novel azidocastasterone derivative as a potential photoaffinity label for the brassinosteroid receptor, SYNLETT, (2), 1999, pp. 201-203
Citations number
30
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
2
Year of publication
1999
Pages
201 - 203
Database
ISI
SICI code
0936-5214(199902):2<201:SOANAD>2.0.ZU;2-N
Abstract
(22R, 23R, 24R)-24-Azido-26,27,28-trinorcastasterone (3) was synthesized fr om stigmasterolin 12 steps via the reaction of Ti(O-iPr)(2)(N-3)(2) with th e corresponding suitably protected threo-22-hydroxy-23,24-epoxide 4.