Regiochemical control in the hydrostannylation of aryl substituted alkynes: A stereoselective synthesis of disubstituted vinylstannanes

Authors
Liron, F Le Garrec, P Alami, M
Citation
F. Liron et al., Regiochemical control in the hydrostannylation of aryl substituted alkynes: A stereoselective synthesis of disubstituted vinylstannanes, SYNLETT, (2), 1999, pp. 246-248
Citations number
14
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
2
Year of publication
1999
Pages
246 - 248
Database
ISI
SICI code
0936-5214(199902):2<246:RCITHO>2.0.ZU;2-E
Abstract
The palladium-catalyzed stereoselective hydrostannylation of various aryl s ubstituted alkynes 1 in THF is described. The reaction is remarkably regios elective and affords mainly to exclusively the alpha-isomers 2 in the case of alkynes bearing electron accepters in para-position and ortho-substitute d alkynes regardless of the electronic nature of the substituent.