N. Kihara et al., SYNTHESIS AND PROPERTIES OF MICROGEL BEARING A MERCAPTO GROUP, Journal of polymer science. Part A, Polymer chemistry, 35(8), 1997, pp. 1443-1451
Vinylbenzyl S-thioacetate (1) was prepared from thioacetic acid and ch
loromethylstyrene. Although bulk polymerization of 1 afforded a crossl
inked polymer, solution polymerization in chlorobenzene afforded a cor
responding soluble polymer. The S-thioacetate group did not react duri
ng the radical polymerization of 1. Bulk copolymerization of 1 with st
yrene afforded a soluble copolymer when the feed ratio of 1 was lower
than 30 mol %. Soap-free emulsion copolymerization of 1, St, divinylbe
nzene, and 2-hydroxyethyl methacrylate (66 : 28 : 1 : 5) was carried o
ut in water using 2,2'-azobis (N,N'-dimethyleneisobutyramidine) dichlo
ride as an initiator to afford uniform spherical microgel 2, whose ave
rage diameter was 135 nm. Aminolysis of 2 with an excess amount of but
ylamine in the presence of sodium tetrahydridoborate followed by treat
ment with hydrochloric acid resulted in complete removal of the acetyl
group to give a slightly distorted spherical microgel (MG-SH) bearing
mercapto group. The average diameter of MG-SH was 165 nm. Trans-ester
ification of p-nitrophenyl acetate (3) in the presence of triethylamin
e was efficiently accelerated by the addition of MG-SH. The radical po
lymerization of methyl methacrylate (MMA) in the presence of suspended
MG-SH in chlorobenzene afforded the MMA-grafted microgel. Although MG
-SH is a crosslinked gel, it acts as a soluble polymer bearing mercapt
o group. (C) 1997 John Wiley & Sons, Inc.