Comparison between calculated and measured thermodynamic data of liquid (Ag,Au,Cu)-Sn-Zn alloys

Citation
M. Peng et al., Comparison between calculated and measured thermodynamic data of liquid (Ag,Au,Cu)-Sn-Zn alloys, CALPHAD, 22(4), 1998, pp. 459-468
Citations number
19
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
ISSN journal
03645916 → ACNP
Volume
22
Issue
4
Year of publication
1998
Pages
459 - 468
Database
ISI
SICI code
0364-5916(199812)22:4<459:CBCAMT>2.0.ZU;2-Y
Abstract
The activity of zinc was measured in a series of liquid alloys in the three ternary systems, Ag-Sn-Zn [94Kar], Au-Sn-Zn [96Kar] and Cu-Sn-Zn [97Pen], with an emf (electromotive force) method. From these measurements and the s lope of the emf vs. temperature (dE/dT) all thermodynamic properties were d erived. The experimental values were compared with calculated results. For these calculations four different models were applied and the thermodynamic data of the binary systems, obtained from the literature, were used.