Characterization of palladium(II) azide and crystal structure of bis(azido)bis(pyridine)palladium(II) and tetramminepalladium tetraazidopalladate(II)

Authors
Beck, W Klapotke, TM Knizek, J Noth, H Schutt, T
Citation
W. Beck et al., Characterization of palladium(II) azide and crystal structure of bis(azido)bis(pyridine)palladium(II) and tetramminepalladium tetraazidopalladate(II), EUR J INORG, (3), 1999, pp. 523-526
Citations number
10
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
14341948 → ACNP
Issue
3
Year of publication
1999
Pages
523 - 526
Database
ISI
SICI code
1434-1948(199903):3<523:COPAAC>2.0.ZU;2-Q
Abstract
Palladium(II) azide (1) was synthesized by reaction of palladium nitrate an d sodium azide. 1 was characterized by AAS, IR, and N-14-NMR spectroscopy. Bis(azido)bis(pyridine)palladium(II) (2) and tetramminepalladium tetraazido palladate(II) (3) were synthesized by a high-yield reaction. Both were char acterized by X-ray structural analysis, IR, Raman, and NMR spectroscopy.