Azinyl sulfides - Part 11 - 1-ethyl-3-methylthio-4-thioxo-1,4-dihydroquinoline or 1-ethyl-3-(methylthio)quinolinium-4-thiolate?

Authors
Maslankiewicz, A Zieba, A Suwinska, K
Citation
A. Maslankiewicz et al., Azinyl sulfides - Part 11 - 1-ethyl-3-methylthio-4-thioxo-1,4-dihydroquinoline or 1-ethyl-3-(methylthio)quinolinium-4-thiolate?, J CHEM CRYS, 28(9), 1998, pp. 701-704
Citations number
24
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
ISSN journal
10741542 → ACNP
Volume
28
Issue
9
Year of publication
1998
Pages
701 - 704
Database
ISI
SICI code
1074-1542(199809)28:9<701:AS-P1->2.0.ZU;2-Y
Abstract
The title compound 1 crystallizes in the monoclinic space group C2/c with a = 16.720(4), b = 8.577(1), c = 15.855(4) Angstrom, and beta = 98.37(1)degr ees. The thiocarbonyl group C-S bond (1.697(4) Angstrom) is longer than tho se of typical carbon-sulfur double bonds in thiones. Bond lengths and bond angles in the pyridine ring of the title compound are close to the values f ound for pyridinium salts.