A direct transform for the nuclear magnetic resonance chemical shift anisotropy

Authors
Citation
Tm. De Swiet, A direct transform for the nuclear magnetic resonance chemical shift anisotropy, J CHEM PHYS, 110(11), 1999, pp. 5231-5237
Citations number
16
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
110
Issue
11
Year of publication
1999
Pages
5231 - 5237
Database
ISI
SICI code
0021-9606(19990315)110:11<5231:ADTFTN>2.0.ZU;2-V
Abstract
A direct transform of the NMR chemical shift anisotropy, operating on data acquired under magic angle spinning conditions, yielding rotationally invar iant quantities, is potentially a source of increased resolution in solid s tate NMR. The mathematical basis for such a transform is discussed by explo iting an analogy with projection reconstruction. A specific example of the kind of pulse sequence required is given, and optimal sampling of the data is discussed. (C) 1999 American Institute of Physics. [S0021-9606(99)00911- 3].