Due to its reliability, simple and portable structure and low costs, the pa
ssive sampler is the ideal measuring device for developing countries. In sp
ite of this, there has been no reporting on its reliability in extremely lo
w temperate areas such as those associated with Northeastern China. The mea
suring of SO2 by passive samplers was attempted at extremely low temperatur
es in the heavy industrialized area of Shenyang, China from December 25 to
28, 1995. The measurements associated with the passive sampler were accompa
nied by reference analysis utilizing conventional gas bubble sampling. The
calibration equation generated from the parallel tests for the passive samp
ler at an extremely low temperature was 100x265xWso(2)/t (-11 approximate t
o-4 degrees C, ppb). The annual average concentration of SO2, as sampled by
the passive sampler, was 79ppb, 33ppb, and 24ppb in heavily polluted, inte
rmediate and reference areas, respectively. The multi-regressional analysis
applied to data collected during the mornings (6:00 am - 8:00 pm), afterno
ons (11:00 am - 1:00 pm) and night (10:00 pm - 12:00 pm) shows that SO2 con
centrations in the morning and night were the most significant variables as
sociated with daily concentration averages.