The objective of this paper, which constitutes a part of the AERONOX p
roject, is the investigation of the potential transformation of the ac
tive species emitted from aircraft into reservoir species. The analysi
s is based on modelling of transformations of the near-field region, 1
km behind a Boeing 767 and a Boeing 747 aircraft. The processes consi
dered are, firstly the dynamics of the jet flow and the jet-wing tip v
ortices interaction and secondly the potential chemical transformation
s of species such as NO, NO2, HNO2, HNO3 and H2SO4. The wake dynamical
processes are performed by using the 3D turbulent Navier-Stokes equat
ions. Chemistry is calculated using a box model including the photoche
mical and heterogeneous reactions. In the jet flow, calculations have
been performed for two engines CFM 56 and RB 211. Temperature fields a
nd dilution profiles are compared. In the wake, the influence of the v
ortical motion on the inboard and outboard jet engines is shown. The c
hemical calculations show that there is a rapid disappearance of OH an
d HO2 at the very beginning of the plume and simultaneous growth of HN
O2 and HNO3. All the main chemical transformations are made in the hot
jet flow. In the limits of the calculations, there is no significant
chemical transformations during the first kilometre behind the Boeing
767, except for OH, HO2 and CH2O2 whose concentrations appear highly d
ependent on the local exhaust NOx concentration. (C) 1997 Elsevier Sci
ence Ltd.