THE PASSIVE TRANSPORT OF NOX EMISSIONS FROM AIRCRAFT STUDIED WITH A HIERARCHY OF MODELS

The passive transport of aircraft emissions of nitrogen oxides (NOx = NO + NO2) has been studied with a hierarchy of models ranging from two -dimensional and three-dimensional chemistry transport models up to th ree-dimensional models of the general circulation. The sink of NOx was parameterized by an exponential decay process with a globally constan t half-lifetime of 10 days. By performing a simple experiment the impo rtance of the various transport processes has been studied. The three- dimensional models show that the monthly mean volume mixing ratio of N Ox varies by a factor of three in the longitudinal direction and the t emporal variability is of the order of 30%. In view of the nonlinearit y of the chemical processes leading to ozone formation in the presence of NOx this implies that the assessment of the effects of subsonic ai rcraft emissions of NOx should be done with three-dimensional models. Vertical redistribution by convection strongly affects the maximum NOx mixing ratio at cruise altitudes, but due to the limited lifetime of NOx of the order of ten days the most important contribution to the mi xing ratio at a certain level usually stems from emissions around that level. The strong static stability in the stratosphere hampers signif icant dispersion of the subsonic aircraft emissions above the height w here the emissions take place for the lifetimes considered here. Some model deficiencies and biases have been identified and discussed. Exam ples are the oscillatory signature of NOx distributions obtained with a spectral advection scheme, the strong diffusion of one of the GCMs i nto the polar regions, and the too intense interhemispheric exchange o f one of the two-dimensional CTMs. For the vertical redistribution of the emissions it may be necessary to include not only updrafts but als o downdrafts in the convective parametrization of the transport model. (C) 1997 Elsevier Science Ltd.