This review describes the advantages and characteristics of employing polym
er electrolytes in solid-state lithium-ion batteries. Criteria for an ideal
polymer electrolyte and the differences between polyelectrolytes are discu
ssed. The emphasis of this article is on plasticized or gelled electrolyte
systems. Hence, the review focuses on four plasticized systems which have r
eceived particular attention from a practical viewpoint, i.e., poly(ethylen
e oxide) (PEO)-, poly(acrylonitrile) (PAN)-, poly(methyl methacrylate) (PMM
A)-, and poly(vinylidene fluoride) (PVdF)-based electrolytes. Some critical
concepts and points associated with this emerging technology that still re
quire attention are discussed in the final part of the review. (C) 1999 Els
evier Science S.A. All rights reserved.