Dg. Ivey et al., PERFORMANCE OF PD-GE BASED OHMIC CONTACTS TO N-TYPE GAAS, Journal of materials science. Materials in electronics, 8(2), 1997, pp. 63-68
The performance of Pd-Ge based ohmic contacts, with and without Ti-Pt
or Ti-Pt-Au capping layers, has been investigated. The contacts were d
eposited by electron beam evaporation, then characterized electrically
using a modified transmission line method (TLM) and structurally usin
g both cross-section and plan-view transmission electron microscopy (T
EM). Although both capped and non-capped contact structures underwent
the same phase transformations during annealing, capped contacts had s
ignificantly better contact resistances (a minimum value of 4 x 10(-7)
Omega cm(2) was achieved)- almost three orders of magnitude better. Th
e superior performance is attributed to the capping layers providing p
rotection for the Pd-Ge layers during contact processing, where the me
tallization was exposed to a CF4-O-2 plasma, oxyen descumming, organic
solvents and deionized water. Non-capped contacts exhibited PdGe deco
mposition and oxidation of exposed Ge. Long-term reliability testing o
f capped contacts showed virtually no change in contact resistance at
235 degrees C (1350 h) and a sevenfold increase after ageing at 290 de
grees C for 370 h. There were no phase changes during ageing; the incr
ease in contact resistance was attributed to interdiffusion between Ge
and GaAs.