EFFECT OF THE STRUCTURAL AND ELECTRONIC CHANGES INDUCED IN POLY(3-METHYLTHIOPHENE), PMET, BY THE MONOMER CONCENTRATION ON THE CHARACTERISTICS OF SPRAYED CDS(AL)-PMET BASED PHOTOVOLTAIC JUNCTIONS
C. Sene et al., EFFECT OF THE STRUCTURAL AND ELECTRONIC CHANGES INDUCED IN POLY(3-METHYLTHIOPHENE), PMET, BY THE MONOMER CONCENTRATION ON THE CHARACTERISTICS OF SPRAYED CDS(AL)-PMET BASED PHOTOVOLTAIC JUNCTIONS, Journal of materials science. Materials in electronics, 8(2), 1997, pp. 85-89
The direct electrodeposition of 3-methylthiophene (MeT) into poly(3-me
thylthiophene) (PMeT) on aluminium-doped cadmium sulphide, CdS(Al), in
the form of sprayed thin films, leads to a Schottky solid-state junct
ion PMeT-CdS(Al) when PMeT is in its highly doped metal-like state. At
tention has been focused on the effect of the parameters of electropol
ymerization of PMeT. The concentration of the monomer produced signifi
cant changes in the photovoltaic parameters of the junction, such as i
deality factor (n), saturation current density (J(0)), barrier height
(Phi(B)), fill factor (FF), series and shunt resistances (R-s, R-sh),
and conversion efficiency (eta).