The effect of indium surface segregation on electronic states and excitonic
properties is investigated experimentally and theoretically in (111)B-grow
n (In,Ga)As/GaAs strained piezoelectric quantum wells. Thermally detected o
ptical absorption and electroreflectance experiments are performed on two s
amples grown by molecular beam; epitaxy and containing 7 and 14 wells, Exci
tonic energies and oscillator strengths are calculated by a variational met
hod within the effective mass approximation. The influence of indium segreg
ation on the piezoelectric field strength and the oscillator strength of ex
citonic transitions is analyzed.