A unique chemisorption structure has been determined for the (root 3 x root
3)R30 degrees H-Be(0001) phase formed at a saturation coverage of 1 ML and
T less than or equal to 270 K. The analysis of low-energy-electron diffrac
tion data shows that 1/3 of the Be top layer atoms are removed to form a ho
neycomb structure of Be vacancies. Each vacancy is decorated by three H ada
toms bonded in tilted bridge sites with a H-Be bond length and angle of 1.5
3 Angstrom (+/- 0.2) and 42 degrees(+/- 10), respectively.