Plasmon excitations in quasi-one-dimensional K0.3MoO3

Citation
M. Sing et al., Plasmon excitations in quasi-one-dimensional K0.3MoO3, PHYS REV B, 59(8), 1999, pp. 5414-5425
Citations number
71
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
PHYSICAL REVIEW B-CONDENSED MATTER
ISSN journal
01631829 → ACNP
Volume
59
Issue
8
Year of publication
1999
Pages
5414 - 5425
Database
ISI
SICI code
0163-1829(19990215)59:8<5414:PEIQK>2.0.ZU;2-C
Abstract
We present an investigation of the plasmon excitations in a quasi-one-dimen sional metal, the blue bronze K0.3MoO3. The dispersion relation along the o ne-dimensional direction, as measured by electron energy-loss spectroscopy in transmission, is quasilinear over a wide momentum range before it exhibi ts a negative curvature. We show that the quasilinear part can be explained within an essentially three-dimensional model based on the random-phase ap proximation. Band-structure effects are thereby considered through the Ehre nreich-Cohen formula, tailor-made to the specific, strongly anisotropic mat erial. From this analysis, we find no hint for exceptional properties cause d by one dimensionality as is currently discussed in the context of photoem ission measurements. The genuine dependence of the plasmon modes on the pro pagation angle relative to the one-dimensional axis is masked by interband transitions lying at about the same energy as the plasmon excitations itsel f.