Charge-ordered state from weak to strong coupling

Citation
S. Ciuchi et F. De Pasquale, Charge-ordered state from weak to strong coupling, PHYS REV B, 59(8), 1999, pp. 5431-5440
Citations number
29
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
PHYSICAL REVIEW B-CONDENSED MATTER
ISSN journal
01631829 → ACNP
Volume
59
Issue
8
Year of publication
1999
Pages
5431 - 5440
Database
ISI
SICI code
0163-1829(19990215)59:8<5431:CSFWTS>2.0.ZU;2-5
Abstract
We apply the dynamical mean field theory to the problem of charge ordering. In this framework we solve the Holstein model for electrons interacting wi th classical phonons in the case of a bipartite lattice. The calculations h as been done at all fillings and temperatures. In the normal state, as well as in the charge-ordered (CO) state, the existence of polarons, i.e., elec trons strongly coupled to local lattice deformation, is associated to the q ualitative behavior of the lattice displacement probability distribution fu nction (LDPDF). Properties of the CO state are qualitatively different in w eak and strong coupling. The weak-coupling regime is characterized by a sin gle-peak LDPDF centered on the sublattice average polarization. The strong- coupling regime is characterized by a double-peak nonsymmetric LDPDF. The s econdary peak is centered on the average polarization of the other sublatti ce indicating a certain amount of defects in the ordered state. This regime can be interpreted as that of a CO phase resulting from the spatial orderi ng of preexisting randomly distributed polarons. The CO critical temperatur e exhibits a maximum in the normal to polaron crossover region. [S0163-1829 (99)00507-X].