"Debye-Scherrer ellipses" from 3D fullerene polymers: An anisotropic pressure memory signature

Citation
L. Marques et al., "Debye-Scherrer ellipses" from 3D fullerene polymers: An anisotropic pressure memory signature, SCIENCE, 283(5408), 1999, pp. 1720-1723
Citations number
28
Categorie Soggetti
Multidisciplinary,Multidisciplinary,Multidisciplinary
Journal title
SCIENCE
ISSN journal
00368075 → ACNP
Volume
283
Issue
5408
Year of publication
1999
Pages
1720 - 1723
Database
ISI
SICI code
0036-8075(19990312)283:5408<1720:"EF3FP>2.0.ZU;2-I
Abstract
High-pressure studies on fullerenes have previously shown the existence of one- and two-dimensional (2D) polymerized C-60 structures. Synchrotron radi ation measurements, performed on C-60 samples quenched from 13 gigapascals and 820 kelvin, yield unambiguous proof for the existence of a three-dimens ional (3D) polymerized C-60 derivative. Moreover, unusual ellipsoidal Debye -Scherrer diffraction patterns are observed, which shows that the giant ani sotropic deformation induced by the nonhydrostatic compression is retained in the quenched samples. The multiple bonding possibilities of the highly s ymmetrical C-60 allow the retention (down to ambient pressure) of the defor mation, a phenomenon reported previously only under high pressure.