Authors
Citation
Kb. Yatsimirskii et Vv. Pavlishchuk, SPECTROSCOPIC AND REDOX BEHAVIOR OF SOME COPPER(II) - THIOETHER COMPLEXES, Journal of coordination chemistry, 37(1-4), 1996, pp. 341-348
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00958972
Volume
37
Issue
1-4
Year of publication
1996
Pages
341 - 348
Database
ISI
SICI code
0095-8972(1996)37:1-4<341:SARBOS>2.0.ZU;2-3
Abstract
The features of electronic spectra and redox chemistry of a number of
Cu(II)-thioether complexes have been examined. The origin of the inten
se absorption in the region around 14,000-16,000 cm(-1) is attributed
to (pi)S --> d(Cu2+) CTB, that obscures the less intense d-d (Cu2+) ba
nd. The relationship between spectral characteristics and redox potent
ials of CuL2(2+/+) couples values is discussed.