THE BONDING OF THIAZOLES TO PLATINUM(II) COMPLEXES - X-RAY CRYSTAL-STRUCTURE OF CIS-[PT(DIMETHYL SULFOXIDE)(THIAZOLE)CL-2] AND TRANS-[PT(DIMETHYL SULFOXIDE)(THIAZOLE)CL-2]

Authors
CORNIA A FABRETTI AC BONIVENTO M CATTALINI L
Citation
A. Cornia et al., THE BONDING OF THIAZOLES TO PLATINUM(II) COMPLEXES - X-RAY CRYSTAL-STRUCTURE OF CIS-[PT(DIMETHYL SULFOXIDE)(THIAZOLE)CL-2] AND TRANS-[PT(DIMETHYL SULFOXIDE)(THIAZOLE)CL-2], Inorganica Chimica Acta, 255(2), 1997, pp. 405-409
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
255
Issue
2
Year of publication
1997
Pages
405 - 409
Database
ISI
SICI code
0020-1693(1997)255:2<405:TBOTTP>2.0.ZU;2-1
Abstract
The crystal structures of neutral cis- and trans-[Pt(dimethyl sulfoxid e) (thiazole)Cl-2] have been determined by X-ray diffraction. The long er C4-C5 bond distance of the N-coordinated thiazole in both the squar e planar complexes, as compared to the free ligand, is interpreted in terms of a negative charge density transfer toward the antibonding orb ital system of the thiazolic ring.