The plasma immersion ion implantation technique was used to implant oxygen
into a-Si:H films, from very low doses to high doses, in order to explore t
he alloying effect of oxygen in a-Si:H. From the electrical characterizatio
n of the synthesized a-SiOx:H films, it was found that oxygen has a very st
rong alloying effect in a-Si:H and that the band gap of a-SiOx:H or the bar
rier height of a metal/a-SiOx:H contact was modified by the oxygen implanta
tion. The a-SiOx:H films investigated have an effective band gap of 1.8-2.3
eV, which is optimum for some industrial applications of amorphous semicon
ductors. However, because of the radiation defects, the conduction mechanis
m of these a-SiOx:H films is dominated by Frenkel-Poole conduction. (C) 199
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