Atomic structure of the SbCu surface alloy: a surface X-ray diffraction study

Citation
I. Meunier et al., Atomic structure of the SbCu surface alloy: a surface X-ray diffraction study, SURF SCI, 422(1-3), 1999, pp. 42-49
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
SURFACE SCIENCE
ISSN journal
00396028 → ACNP
Volume
422
Issue
1-3
Year of publication
1999
Pages
42 - 49
Database
ISI
SICI code
0039-6028(19990222)422:1-3<42:ASOTSS>2.0.ZU;2-3
Abstract
The dissolution at 400 degrees C of an antimony layer deposited at room tem perature on a Cu(111) substrate leads to a surface alloy with a p(root 3x r oot 3)R 30 degrees x 30 degrees superstructure and a Sb composition of 1/3. We present here a structural study of this Sb-Cu compound by surface X-ray diffraction (SXRD). The best agreement is obtained for a Cu,Sb surface laye r with Sb atoms substituting 1/3 of the Cu atoms, over an essentially unper turbed Cu(111) plane. The largest relaxation is undergone by the Sb atoms w hich rise by 0.32+0.02 Angstrom over the mean plane of its Cu neighbours. N o substantial in-plane relaxations were observed. (C) 1999 Elsevier Science B.V. All rights reserved.