Ak. Varshney et al., Synthesis and spectral studies of some tin(II) and tin(IV) macrocyclic Schiff base complexes, SYN REAC IN, 29(2), 1999, pp. 245-254
Citations number
13
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
The present paper is a report on the synthesis and characterisation of some
tin(Ii) and tin(IV) macrocyclic Schiff base complexes. These complexes hav
e been prepared by the reaction of tin dichloride, tin tetrachloride and di
methyItin dichloride with 1,3-diaminopropane and benzil or m-phenylenediami
ne and acetylacetone in oxygen-free nitrogen atmosphere using THF as the re
action medium. On the basis of elemental analyses, conductance measurements
, molecular weight determinations, and Sn-119 Mossbauer, electronic, infrar
ed,H-1 NMR and Sn-119 NMR spectral studies, structures have been proposed f
or these new complexes.