Citation
Ia. Koval et al., Directed synthesis, spectral and magnetochemical characteristics of the new multispin (S=7/2, T = 292 K) trinuclear complex, TEOR EKSP K, 34(6), 1998, pp. 351-354
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA
ISSN journal
04972627
→ ACNP
Volume
34
Issue
6
Year of publication
1998
Pages
351 - 354
Database
ISI
SICI code
0497-2627(1998)34:6<351:DSSAMC>2.0.ZU;2-J
Abstract
The new trinuclear complex K{(CoTp<SUP>t-Bu</SUP>)[Fe(CN)<INF>6</INF>](CoTp
<SUP>t-Bu</SUP>)}, in which starting motives are linked by CN<SUP>-</SUP> b
ridges, was<SUP></SUP> synthesized by direct sewing of mononuclear complexe
s, one of which was [Fe(CN)<INF>6</INF>]<SUP>3-</SUP>, and the other was co
balt(II) tris-(3-tretbuthylpyrazol-l-yl)borate. Magnetic moment of K{(CoTp<
SUP>t-Bu</SUP>)[Fe(CN)<INF>6</INF>](CoT p<SUP>t-Bu</SUP>)} at 292 K is 8.07
mu<INF>B</INF> (S=7/2) that testifies about the absence of antiferromagnet
ic interactions in trinuclear complex.