A novel Fremy's salt-mediated oxidation and rearrangement of anilines intoamino ortho-diketones. Applications to the synthesis of pyrrolobenzodiazepines

Authors
Kraus, GA Selvakumar, N
Citation
Ga. Kraus et N. Selvakumar, A novel Fremy's salt-mediated oxidation and rearrangement of anilines intoamino ortho-diketones. Applications to the synthesis of pyrrolobenzodiazepines, TETRAHEDR L, 40(11), 1999, pp. 2039-2040
Citations number
10
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
11
Year of publication
1999
Pages
2039 - 2040
Database
ISI
SICI code
0040-4039(19990312)40:11<2039:ANFSOA>2.0.ZU;2-A
Abstract
The reaction of anilines 1, 3, and 5 with 4.4 equivalents of Fremy's salt a ffords ortho-quinones in good yields via a one-pot five-step sequence. (C) 1999 Elsevier Science Ltd. All rights reserved.