New, practical and effective sources of fluoride ion for desilylation to form carbon anions

Authors
Busch-Petersen, J Bo, YX Corey, EJ
Citation
J. Busch-petersen et al., New, practical and effective sources of fluoride ion for desilylation to form carbon anions, TETRAHEDR L, 40(11), 1999, pp. 2065-2068
Citations number
13
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
11
Year of publication
1999
Pages
2065 - 2068
Database
ISI
SICI code
0040-4039(19990312)40:11<2065:NPAESO>2.0.ZU;2-O
Abstract
Suspensions of powdered glassy solids prepared by fusion of 1 : 1 mixtures of CsF-CsOH and CsF-CsCl effectively catalyze the generation of enolates, a cetylide and other anions from trimethylsilylated precursors. (C) 1999 Else vier Science Ltd. All rights reserved.