(-)-sparteine-mediated stereoselective intramolecular conjugate addition reactions of dienes and enynes

Authors
Oestreich, M Hoppe, D
Citation
M. Oestreich et D. Hoppe, (-)-sparteine-mediated stereoselective intramolecular conjugate addition reactions of dienes and enynes, TETRAHEDR L, 40(10), 1999, pp. 1881-1884
Citations number
25
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
10
Year of publication
1999
Pages
1881 - 1884
Database
ISI
SICI code
0040-4039(19990305)40:10<1881:(SICAR>2.0.ZU;2-Y
Abstract
Enantioenriched carbanionic pairs generated by the asymmetric deprotonation of carbamate eaters with the chiral base s-butyllithium/(-)-sparteine unde rgo smoothly intramolecular conjugate addition reactions to dienes and enyn es in high yields. (C) 1999 Elsevier Science Ltd. All rights reserved.