A facile synthesis of 2,6-bis-trialkylsilyl-4H-pyranes from 1,5-bis-acylsilanes

Citation
D. Saleur et al., A facile synthesis of 2,6-bis-trialkylsilyl-4H-pyranes from 1,5-bis-acylsilanes, TETRAHEDR L, 40(10), 1999, pp. 1885-1886
Citations number
10
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
10
Year of publication
1999
Pages
1885 - 1886
Database
ISI
SICI code
0040-4039(19990305)40:10<1885:AFSO2F>2.0.ZU;2-J
Abstract
The new 2,6-bis-trialkylsilyl-4H-pyranes were easily prepared from 1,5-bisd ithianes via a two steps sequence of dethioketalization and cyclodehydratio n in the presence of a catalytic amount of p-toluenesulfonic acid. (C) 1999 Elsevier Science Ltd. All rights reserved.