Citation
Ia. Razak et al., Trichloro[methylenebis(diphenylphosphine oxide-O)]antimony(III), ACT CRYST C, 55, 1999, pp. 172-174
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701
→ ACNP
Volume
55
Year of publication
1999
Part
2
Pages
172 - 174
Database
ISI
SICI code
0108-2701(19990215)55:<172:TO>2.0.ZU;2-C
Abstract
The asymmetric unit of the title complex, [SbCl3{[(C6H5)(2)PO](2)CH2}], com
prises two independent molecules, in both of which the Sb atoms are in flat
tened square-pyramidal environments, with the basal planes each defined by
two O and two Cl atoms, and the apical atom being Cl in each molecule. The
geometry can alternatively be described as distorted octahedral as a result
of coordination by a sixth (Cl) atom at a longer distance.