Aquabis(2,2 '-bipyridine-N,N ')(perchlorato-O)manganese(II) perchlorate

Authors
Rodriguez-Martin, Y Gonzalez-Platas, J Ruiz-Perez, C
Citation
Y. Rodriguez-martin et al., Aquabis(2,2 '-bipyridine-N,N ')(perchlorato-O)manganese(II) perchlorate, ACT CRYST C, 55, 1999, pp. 186-188
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
2
Pages
186 - 188
Database
ISI
SICI code
0108-2701(19990215)55:<186:A''P>2.0.ZU;2-L
Abstract
The crystal structure of the title compound, [Mn(ClO4)(C10H8N2)(2)(H2O)]ClO 4, contains monomeric [Mn(bipy)(2)(ClO4)(H2O)](+) cations (bipy is 2,2'-bip yridine) in which the Mn-II ion is surrounded by a pair of chelating bipy l igands [Mn-N 2.222(5)-2.228 (5) Angstrom], an aqua ligand [Mn-O 2.142(4) An gstrom] and a perchlorate ligand [Mn-O 2.289(5)Angstrom] in a distorted oct ahedral arrangement. Adjacent cations are linked into dimers by pairs of O ... O hydrogen bonds [O ... O 2.795 (7) Angstrom].