This paper reports the upconversion luminescence phenomenon of crystal ErP5
O14 in ultraviolet to blue-green wave range induced by red DCM dye laser. T
he upconversion passage of each upconversion fluorescence is confirmed. It
is found that the upconversion mechanism is mainly non-resonant upconversio
n energy transfers between rare earth ions when laser wavelength is near 65
0 nm. It is very interesting that the non-resonant upconversion energy tran
sfer is achieved directly through a kind of coupling state of rare earth io
n cluster and the ions do not exchange their phonon energy with crystal lat
tice.