Formation of an ordered surface structure in La0.5Ca0.5MnO3 films due to th
e mismatch of the thermal expansion coefficient between the film and the su
bstrate has been investigated. The surface pattern consists of grain chains
located on regular orthogonal cracks. The cracks serve as weak-link grain
boundaries, and unusually enhanced low-field magnetoresistance (-14.4% in 4
00 Oe at 90 K) has been observed, which may be explained by spin-polarized
tunneling across the grain boundaries. (C) 1999 American Institute of Physi
cs. [S0003-6951(99)02311-6].