Lb. Han et M. Tanaka, Transition metal-catalysed addition reactions of H-heteroatom and inter-heteroatom bonds to carbon-carbon unsaturated linkages via oxidative additions, CHEM COMMUN, (5), 1999, pp. 395-402
Oxidative addition of inter-heteroatom bonds comprising B, Si, Ge, Sn, P, S
, Se and Te with late transition metal complexes readily takes place at roo
m temperature and triggers a variety of catalytic additions of the bonds to
carbon-carbon unsaturated linkages. The new catalytic reactions are regio-
and stereoselective and provide high yield syntheses of synthetically vers
atile heteroatom compounds.