Radical cation Diels-Alder reaction between indoles and exocyclic 1,3-dienes with incorporated intentional cleaving points

Authors
Peglow, T Blechert, S Steckhan, E
Citation
T. Peglow et al., Radical cation Diels-Alder reaction between indoles and exocyclic 1,3-dienes with incorporated intentional cleaving points, CHEM COMMUN, (5), 1999, pp. 433-434
Citations number
27
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
5
Year of publication
1999
Pages
433 - 434
Database
ISI
SICI code
1359-7345(19990307):5<433:RCDRBI>2.0.ZU;2-F
Abstract
A photoinduced electron transfer catalyzed radical cation Diels-Alder react ion between exocyclic dienes, containing an N-O or N-N bond as an intention al cleaving point in the ring moiety, and indoles yields, after cleavage of the N-O or N-N bond, highly functionalized tetrahydrocarbazole derivatives , products of a formal Diels-Alder reaction between indole and open chain 1 ,3-dienes.