Phospha-alkyne hydro-osmiation: synthesis of [Os{kappa P-1,kappa P-1 '-P=CRP(=CHR)}Cl(CO)(PPh3)(2)](R = CMe3)

Authors
Hill, AF Jones, C Wilton-Ely, JDET
Citation
Af. Hill et al., Phospha-alkyne hydro-osmiation: synthesis of [Os{kappa P-1,kappa P-1 '-P=CRP(=CHR)}Cl(CO)(PPh3)(2)](R = CMe3), CHEM COMMUN, (5), 1999, pp. 451-452
Citations number
16
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
5
Year of publication
1999
Pages
451 - 452
Database
ISI
SICI code
1359-7345(19990307):5<451:PHSO[P>2.0.ZU;2-J
Abstract
The reaction of [OsHCl(CO)(PPh3)(2)(BTD)] (BTD = 2,1,3-benzothiadiazole) wi th P=CCMe3 provides the novel complex [Os{kappa(1)P,kappa(1)P'-P=CRP(=CHR)C l(CO)(PPh3)(2)] (R = CMe3) which features both phospha-alkenyl and phosphaa lkene donors within the same metallacycle.