Bidirectional asymmetric allylboration and the synthesis of C-2 symmetric 3-methylenepentane-1,5-diols

Authors
Barrett, AGM Braddock, DC de Koning, PD
Citation
Agm. Barrett et al., Bidirectional asymmetric allylboration and the synthesis of C-2 symmetric 3-methylenepentane-1,5-diols, CHEM COMMUN, (5), 1999, pp. 459-460
Citations number
18
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
5
Year of publication
1999
Pages
459 - 460
Database
ISI
SICI code
1359-7345(19990307):5<459:BAAATS>2.0.ZU;2-V
Abstract
The double allylboration of aldehydes using 1,3-bis(diisopinocampheylboryl) -2-methylenepropane under Brown's salt-free conditions provides Ct symmetri c 3-methylenepentane-1,5-diols in excellent enantiomeric excess.