pi-mediated rearrangements and 1,2-H shifts of indanylcarbenes

Authors
Moss, RA Ma, W Sauers, RR
Citation
Ra. Moss et al., pi-mediated rearrangements and 1,2-H shifts of indanylcarbenes, CHEM COMMUN, (5), 1999, pp. 467-468
Citations number
22
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
5
Year of publication
1999
Pages
467 - 468
Database
ISI
SICI code
1359-7345(19990307):5<467:PRA1SO>2.0.ZU;2-5
Abstract
Absolute rate constants determined for 1,2-C and 1,2-H migrations of cyclob utyl-, cyclopentyl-, benzocyclobutenyl- and benzocyclopentenyl-(chloro)- or -(acetoxy)-carbenes reveal that 'phenyl' carbon migrations are preferred t o alternative 1,2-C shifts due to pi-electronic effects.