Tgn. Babu et al., SYNTHESIS AND CHARACTERIZATION OF BA2-XSRXEUSBO6 CERAMIC SUBSTRATES FOR YBCO FILMS, Journal of Materials Science, 32(7), 1997, pp. 1759-1763
A group of complex perovskites, Ba2-xSrxEuSbO6 (where x = 0, 1 and 2)
was synthesized and sintered as single-phase materials for their use a
s substrates for YBCO superconductor films. These compounds have a com
plex cubic perovskite (A(2)BB'O-6) crystal structure with lattice cons
tant in the range 0.85-0.83 nm. The values of dielectric constant and
loss factor of Ba2-xSrxEuSbO6 compounds are in the range suitable for
their use as substrates for microwave applications of superconductor f
ilms. The dielectric constant decreases with increase of strontium con
tent. No chemical reaction was observed between YBCO and Ba2-xSrxEuSbO
6 ceramics even when they were mixed in composites of the form 80 vol%
YBCO-20 vol% Ba2-xSrxEuSbO6 and processed under severe heat treatment
. Addition of up to 20 vol% Ba2-xSrxEuSbO6 to YBCO showed no detriment
al effect on superconducting properties of YBCO. The YBCO thick films
developed on sintered specimens by dip coating were textured and showe
d (00/) orientation with T-c(0) = 92 K.