Dissolution kinetics of magnesite mineral in water saturated by chlorine gas

Citation
H. Ozbek et al., Dissolution kinetics of magnesite mineral in water saturated by chlorine gas, HYDROMETALL, 51(2), 1999, pp. 173-185
Citations number
14
Categorie Soggetti
Metallurgy
Journal title
HYDROMETALLURGY
ISSN journal
0304386X → ACNP
Volume
51
Issue
2
Year of publication
1999
Pages
173 - 185
Database
ISI
SICI code
0304-386X(199902)51:2<173:DKOMMI>2.0.ZU;2-V
Abstract
In this study, the dissolution kinetics of magnesite mineral with Cl-2 gas in aqueous media were investigated. The effects of reaction temperature, pa rticle size, solid-to-liquid ratio, gas flow rate and stirring speed on the dissolution process were determined. It was observed that the dissolution of the magnesite mineral increased with increasing reaction temperature, ga s flow rate and stirring speed and with decreasing particle size and solid- to-liquid ratio. By analysis of the experimental data using heterogeneous k inetic models, it was determined that the dissolution process is controlled by resistance of the chemical surface reaction for range 12 degrees-40 deg rees C and film diffusion for range 40 degrees-70 degrees C. (C) 1999 Elsev ier Science B.V. All rights reserved.