Gallium(III) chloride benzotriazole chemistry: variation of product as a function of metal-to-ligand reaction ratio; preparation, structure and properties of a tetrahedral adduct and the first example of a GaX3L2 trigonal-bipyramidal complex

Authors
Zanias, S Raptopoulou, CP Terzis, A Zafiropoulos, TF
Citation
S. Zanias et al., Gallium(III) chloride benzotriazole chemistry: variation of product as a function of metal-to-ligand reaction ratio; preparation, structure and properties of a tetrahedral adduct and the first example of a GaX3L2 trigonal-bipyramidal complex, INORG CH C, 2(2), 1999, pp. 48-51
Citations number
17
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
2
Issue
2
Year of publication
1999
Pages
48 - 51
Database
ISI
SICI code
1387-7003(199902)2:2<48:GCBCVO>2.0.ZU;2-R
Abstract
The I : I and 1 :3 reactions of GaCl3 with benzotriazole (Hbta 1 in toluene -diethyl ether afforded the pseudotetrahedral adduct [GaCl3( Hbta)] (1) and the novel trigonal-bipyramidal species [GaCl3(Hbta)(2)] (2), respectively, crystal structures of which have been determined. Some spectroscopic prope rties of the prepared complexes are also discussed. (C) 1999 Elsevier Scien ce S.A. All rights reserved.