Activity coefficients of Al(ClO4)(3) in aqueous solutions: a reexamination

Authors
Molero, M Gonzalez-Arjona, D Calvente, JJ Lopez-Perez, G
Citation
M. Molero et al., Activity coefficients of Al(ClO4)(3) in aqueous solutions: a reexamination, J ELEC CHEM, 460(1-2), 1999, pp. 100-104
Citations number
23
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
ISSN journal
15726657 → ACNP
Volume
460
Issue
1-2
Year of publication
1999
Pages
100 - 104
Database
ISI
SICI code
Abstract
A reexamination of the published activity coefficients of AI(CIO,), in aque ous solutions (E. Kalman, G. Horn, K. Schwabe, Z. Phys. Chem. (Leipzig), 24 4 (1970) 106) is given. A procedure for the estimation of activity coeffici ents of electrolytes is proposed. The method combines experimental osmotic coefficients and a theory based on the primitive model. This strategy provi des suitable results, especially for asymmetrical electrolytes. (C) 1999 El sevier Science S.A. All rights reserved.