Citation
Ej. Fernandez et al., Phosphinethiolate tin(IV)-11 group-metal derivatives. X-ray structure of [Au2Sn(Bu-t)(2)(C6F5)(2)(SC6H4PPh2)(2)], J ORGMET CH, 574(2), 1999, pp. 207-212
Citations number
44
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X
→ ACNP
Volume
574
Issue
2
Year of publication
1999
Pages
207 - 212
Database
ISI
SICI code
0022-328X(19990218)574:2<207:PTGDXS>2.0.ZU;2-1
Abstract
[SnR2Cl2] reacts with (SC6H4PPh2)(-) giving [SnR2(SC6H4PPh2)(2)] (R = Me, B
u-t, Ph) (1a-c). These compounds can displace tetrahydrothiophene from [Au(
C6F5)(tht)] or [Au(tht)(2)]ClO4 or reacts with AgClO4. Complexes [SnR2{(SC6
H4PPh2)Au(C6F5)}(2)] (2a-c) and [SnR2(SC6H4PPh2)(2)M]ClO4 (M = Au 3a-c; M =
Ag 4a-c) are obtained. The crystal structure of [Sn(Bu-t)(2){(SC6H4PPh2)Au
(C6F5)}(2)] (2b) has been established by X-ray diffraction. (C) 1999 Elsevi
er Science S.A. All rights reserved.