B. Scaillet et Bw. Evans, The 15 June 1991 eruption of Mount Pinatubo. I. Phase equilibria and pre-eruption P-T-fO(2)-fH(2)O conditions of the dacite magma, J PETROLOGY, 40(3), 1999, pp. 381-411
Crystallization experiments were carried out on a representative sample of
the crystal-rich dacite ejected during the 15 June 1991 eruption of Mt. Pin
atubo, to define the pre-eruption conditions of this major volcanic ev ent.
Experiments were performed in the temperature and pressure range of 750-90
0 degrees C and 220-390 MPa, respectively. Redox conditions were varied bet
ween those of the NNO (nickel-nickel oxide) buffer and 2.7 log fO(2) units
above (NNO + 2.7). Melt water contents ranged from 3 to 7 wt% (H2O saturati
on). Phase equilibria at 220 MPa reproduce the phase assemblage of the magm
a only at temperatures below 780 degrees C and water-rich conditions: melt
H2O content > 6 wt%, or XH2Ofluid > 0.80. Phase abundances and the composit
ions of hornblende, plagioclase, and melt indicate that the eruption tapped
a magma body that was at a temperature of 760 +/- 20 degrees C and a press
ure in the range of 220-180 MPa, with melt H2O contents between 6 and 6.5 w
t%, that is, XH2Ofluid > 0.88. Thermodynamic calculations constrain CO2 in
the melt to be <100 ppm. Comparison between natural and experimental Fe-Ti
oxide compositions indicate that fO(2) was in the range NNO + 1.5 to NNO 1.7. Current calibrations of the Fe-Ti oxide thermobarometer are not approp
riate for oxidizing conditions, and overestimate both T and fO(2) when fO(2
) is greater than NNO + 1.5. Compositional zoning of plagioclase reflects c
rystallization over 150 degrees C (900-750 degrees C), and implies conditio
ns close to, or at, H2O saturation throughout crystallization in the upper-
crustal magma chamber. Although continuous magma replenishment probably occ
urred, the injected magma must have had the same bulk composition (includin
g the same melt H2O content) as the erupted dacite to preserve the linear r
elationship observed between An and Or contents of the plagioclase. Composi
tional zoning of hornblende is consistent either with an early crystallizat
ion event at similar to 400 MPa and 840-900 degrees C, or with mixing event
s before eruption. The experiments show that addition of S leads to an incr
ease in the mg-number of hornblende in the redox range where pyrrhotite occ
urs (less than or equal to NNO + 1.4). The lack of Mg-rich overgrowth on ho
rnblende shows that if sulfur was introduced into the magma in the course o
f its crystallization, such as by volatile infiltration from an underlying,
triggering basalt magma, then it must have occurred when the dacite was al
ready oxidized.