The absence of a discommensuration lattice in the incommensurate phase of Rb2ZnCl4

Citation
Ay. Babkevich et Ra. Cowley, The absence of a discommensuration lattice in the incommensurate phase of Rb2ZnCl4, J PHYS-COND, 11(7), 1999, pp. 1639-1655
Citations number
47
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
JOURNAL OF PHYSICS-CONDENSED MATTER
ISSN journal
09538984 → ACNP
Volume
11
Issue
7
Year of publication
1999
Pages
1639 - 1655
Database
ISI
SICI code
0953-8984(19990222)11:7<1639:TAOADL>2.0.ZU;2-F
Abstract
X-ray scattering close to the lock-in temperature T-L has been measured as a function of temperature to investigate whether the discommensuration latt ice is a useful description of the structure of Rb2ZnCl4. We review differe nt models for the incommensurate structure and discuss how they might be di stinguished by a scattering experiment. Our results are compared with earli er published x-ray measurements and with those obtained from nuclear spin-r esonance techniques. All of the x-ray results suggest that higher harmonics of the scattering measured in the a*/c* and b*/c* planes are much weaker t han predicted by the abrupt-discommensuration model. We conclude from the m easurements that this theory does not provide an adequate description of th e experimental results close to the lock-in transition.